Barcelona vs Olympiacos Prediction, Betting Tips, Lineups & Odds | 21 Oct 2025
Champions League Betting Preview: Barcelona vs Olympiacos
Spanish La Liga team Barcelona host Greek Super League club Olympiacos in this Champions League match at Camp Nou, with kick-off set for 12:45 on Tuesday 21 October. Our betting preview features expert predictions, betting tips, the latest odds, H2H stats, team news and both predicted and confirmed lineups.
Back Barca For a Convincing Win
Barcelona -2.25 are available at -102 on the Asian Handicap and we need a three-goal winning margin to land a full return. However, we get half our stake returned if the favourites win by two goals against Olympiacos.
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Each Team Bidding to Secure Another Win
Barcelona won their last game, beating Girona 2-1 at Estadio Olimpico Lluis Companys in La Liga. Los Culés had nine shots on target and boasted 68% possession, with Pedri and Ronald Araujo scoring one goal apiece.
Olympiacos won their previous game. It was on the road where Larissa were beaten 2-0 at Alkazar Stadium in the Super League. Jose Luis Mendilibar's team managed four shots on goal and enjoyed 57% possession, with Ayoub El Kaabi scoring twice.
| Champions League | G | W | D | L | GF | GA | GD | GD | P | |
|---|---|---|---|---|---|---|---|---|---|---|
| 16 |  Barcelona |
2 | 1 | 0 | 1 | 3 | 3 | 0 | 3:3 | 3 |
| 29 |  Olympiacos |
2 | 0 | 1 | 1 | 0 | 2 | -2 | 0:2 | 1 |
8 wins, 1 loss and 1 draw, averaging 2.7 goals from 20.2 attempts and 8.3 shots on goal. Barca have had 71.3% possession and 7.3 corners per match. On average, the opposition have scored 1.0 goals from 7.4 attempts and 3.0 shots on goal, while earning 3.9 corners.
Robert Lewandowski leads the way with 6 goals, while Ferran Torres and Raphinha have scored 4 and 3 respectively. Lamine Yamal and Marcus Rashford are tied for the most assists on 4, with goalie Joan Garcia managing 3 clean sheets.
Olympiacos – Last 10 League & Champions League GamesOlympiacos have won 8, lost 1 and drawn 1, with an average of 2.3 goals from 4.8 shots on goal and 9.3 attempts. The Piraeus outfit have averaged 56.1% possession, 6.4 corners taken and 3.3 corners against, while conceding 0.7 goals from 3.5 shots on goal and 5.9 attempts.
Ayoub El Kaabi has landed 7 goals, Chiquinho 5, with Panagiotis Retsos and two others scoring 2. Francisco Ortega, Ayoub El Kaabi and Christos Mouzakitis have clocked up 2 assists each in the previous 10 games.
Predicted & Confirmed Lineups
Barcelona predicted lineup (4-2-3-1): Wojciech Szczesny (GK), Jules Kounde, Ronald Araujo, Pau Cubarsí, Gerard Martin, Pedri, Frenkie De Jong, Lamine Yamal, Fermín López, Álex Balde, Marcus Rashford.
Olympiacos predicted lineup (4-2-3-1): Konstantinos Tzolakis (GK), Costinha, Panagiotis Retsos, Lorenzo Pirola, Francisco Ortega, Dani García, Santiago Hezze, Gelson Martins, Chiquinho, Daniel Podence, Ayoub El Kaabi.
Barcelona vs Olympiacos Prediction & Betting Tips
Our Barcelona vs Olympiacos betting guide delivers expert insight, including a main match pick, our corners angle, scoreline advice, standout player props and bet builder recommendations. Dive into each section below for more.
Match Prediction
Barcelona should pack a punch in this Champions League game. We’ll take them at -2.25 which means getting generous odds of -102 and there’s every chance that the favourites can oblige with a handsome win.
Our football picks always stem from lots of research and it begins by looking at the latest Champions League team news and current form. When we have a strong view of what might happen, we match up the latest numbers.
Key Barcelona vs Olympiacos Champions League & league stats:
Barca -2.25 Probability
The best betting apps make it a 50.5% chance that our pick is settled as a winner. However, our experts think that the probability is close to 60% taking all factors into consideration. This wager can therefore be backed with confidence.
There is regularly the choice to sell goals which potentially provides the chance to secure a larger return. Alternatively, buying goals is a safer option at skinnier odds.
Before placing your wager, discover the best bonus deals. Our guide highlights the most rewarding betting offers available.
Correct Score Prediction
3
-
0
Olympiacos
We’re betting on Barcelona to secure a 3-0 winning scoreline. Odds of +575 can be taken and it’s great fun to predict a correct score and hopefully land a winner.
Player Prop Picks
Lamine Yamal (Barcelona) hasn't covered the 1.5 shots on goal total in three straight games. We’ll go with the latest numbers and back him to go under the Shots on Target line at odds of -141.
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Pedri (Barcelona) has scored two goals in his past ten games. Based on the numbers, we are looking to bet the +525 for him to find the net on the Anytime Goalscorer market.
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Corners Prediction
Olympiacos have had over 2.5 corners in ten consecutive games, while the previous 5 Barcelona matches have seen them concede an average of 5.60 corners. We think it’s possible that Olympiacos will cover the Team Corners line and there are odds of -104 available.
Barcelona
Olympiacos
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Bet Builder Tips
Our same-game multi selections include Barcelona with an Asian Handicap of -2.25, No on the Both Teams to Score market combined with Lamine Yamal (Barcelona) to tally under 1.5 shots on target.
Should you want to back different outcomes for the same football game, then a bet builder will suit your needs. It’s a great bet to have if you’re confident of certain outcomes, especially as the price for each selection is combined.
Barcelona vs Olympiacos Odds
The odds are updated on a frequent basis. You might therefore find that they are different to the ones listed for the above betting predictions.
Barcelona Big Favourites on the Full-Time Result Market
The latest Full-Time Result odds give Barcelona a 85% chance of triumphing which means that they’re overwhelming -588 favourites to win this Champions League clash. Olympiacos are the outsiders at +1400 which suggests a low likelihood of winning.
If you want to back the favourites to be ahead by the break, then Barca are -192 on the Half-Time Result market. Alternatively, Olympiacos are +800 and the draw is priced at +225.
The odds suggest that Over 2.5 Goals is a strong probability in this exciting contest. A different angle is going for a BTTS wager and there’s -149 available for Both Teams to Score No.
If you head to the best football betting sites, you can take your pick when it comes to Champions League matches. The hundreds of markets always ensure lots of choice.
Lamine Yamal Favourite to Be First Goalscorer
Lamine Yamal is the market leader to be First Goalscorer at +350. Alternatively, there’s the chance to back him to find the net at any stage at +112.
Latest Champions League and domestic league stats. Full Time Result, Goals, Corners and Possession.
Barcelona Stats
Olympiacos Stats
- 8 wins, 1 defeat and 1 draw in the previous 10 matches
- 8 wins, 1 defeat and 1 draw in the previous 10 home matches
- 8 wins, 1 defeat and 1 draw in the previous 10 matches
- 7 wins, 2 defeats and 1 draw in the previous 10 away matches
- An average of 2.70 goals scored and 1.00 conceded in the previous 10 matches
- An average of 2.90 goals scored and 1.30 conceded in the previous 10 home matches
- An average of 3.70 goals per game in the previous 10 matches
- An average of 4.20 goals per game in the previous 10 home matches
- BTTS Yes in 6 of the previous 10 matches
- BTTS Yes in 7 of the previous 10 home matches
- Over 2.5 Goals in 9 of the previous 10 matches
- Over 2.5 Goals in 8 of the previous 10 home matches
- An average of 2.30 goals scored and 0.70 conceded in the previous 10 matches
- An average of 1.60 goals scored and 0.50 conceded in the previous 10 away matches
- An average of 3.00 goals per game in the previous 10 matches
- An average of 2.10 goals per game in the previous 10 away matches
- BTTS Yes in 4 of the previous 10 matches
- BTTS Yes in 3 of the previous 10 away matches
- Over 2.5 Goals in 4 of the previous 10 matches
- Over 2.5 Goals in 3 of the previous 10 away matches
- An average of 7.30 corners awarded and 3.90 corners conceded in the last 10 matches
- An average of 8.80 corners awarded and 2.50 corners against in the last 10 home matches
- An average of 11.20 corners awarded in the last 10 matches
- An average of 11.30 corners awarded in the last 10 home matches
- Had the most corners in 8 and least corners in 2 of the last 10 matches
- Had the most corners in 10 and least corners in 0 of the last 10 home matches
- An average of 6.40 corners awarded and 3.30 corners conceded in the last 10 matches
- An average of 4.50 corners awarded and 2.90 corners against in the last 10 away matches
- An average of 9.70 corners awarded in the last 10 matches
- An average of 7.40 corners awarded in the last 10 away matches
- Had the most corners in 7 and least corners in 2 of the last 10 matches
- Had the most corners in 7 and least corners in 3 of the last 10 away matches
- An average of 71.30% possession in the last 10 matches
- An average of 71.10% possession in the last 10 home matches
- Most possession in 10 of the last 10 matches
- Most possession in 10 of the last 10 home matches
Barcelona vs Olympiacos Lineups & Team News
Know who’s in and who’s out for Barca vs Olympiacos before making your bets. We’ll have the predicted and confirmed Champions League lineups for you plus all the latest on player injuries.
Barcelona Predicted Lineup 4-2-3-1
Olympiacos Predicted Lineup 4-2-3-1
Barcelona Predicted Lineup 4-2-3-1
Olympiacos Predicted Lineup 4-2-3-1
Previous Barcelona Lineups
Previous Olympiacos Lineups
Barcelona Squad
Olympiacos Squad| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Bayern Munich | 2 | 2 | 0 | 0 | 8:2 | 6 |
| 2 | Real Madrid | 2 | 2 | 0 | 0 | 7:1 | 6 |
| 3 | PSG | 2 | 2 | 0 | 0 | 6:1 | 6 |
| 4 | Inter Milan | 2 | 2 | 0 | 0 | 5:0 | 6 |
| 5 | Arsenal | 2 | 2 | 0 | 0 | 4:0 | 6 |
| 6 | Qarabag FK | 2 | 2 | 0 | 0 | 5:2 | 6 |
| 7 | Dortmund | 2 | 1 | 1 | 0 | 8:5 | 4 |
| 8 | Man City | 2 | 1 | 1 | 0 | 4:2 | 4 |
| 9 | Tottenham | 2 | 1 | 1 | 0 | 3:2 | 4 |
| 10 | Atlético Madrid | 2 | 1 | 0 | 1 | 7:4 | 3 |
| 11 | Newcastle | 2 | 1 | 0 | 1 | 5:2 | 3 |
| 12 | Marseille | 2 | 1 | 0 | 1 | 5:2 | 3 |
| 13 | Club Brugge | 2 | 1 | 0 | 1 | 5:3 | 3 |
| 13 | Sporting | 2 | 1 | 0 | 1 | 5:3 | 3 |
| 15 | Frankfurt | 2 | 1 | 0 | 1 | 6:6 | 3 |
| 16 | Barcelona | 2 | 1 | 0 | 1 | 3:3 | 3 |
| 17 | Liverpool | 2 | 1 | 0 | 1 | 3:3 | 3 |
| 18 | Chelsea | 2 | 1 | 0 | 1 | 2:3 | 3 |
| 19 | Napoli | 2 | 1 | 0 | 1 | 2:3 | 3 |
| 20 | Union S-G | 2 | 1 | 0 | 1 | 3:5 | 3 |
| 21 | Galatasaray | 2 | 1 | 0 | 1 | 2:5 | 3 |
| 22 | Atalanta | 2 | 1 | 0 | 1 | 2:5 | 3 |
| 23 | Juventus | 2 | 0 | 2 | 0 | 6:6 | 2 |
| 24 | Bodo/Glimt | 2 | 0 | 2 | 0 | 4:4 | 2 |
| 25 | Leverkusen | 2 | 0 | 2 | 0 | 3:3 | 2 |
| 26 | Villarreal | 2 | 0 | 1 | 1 | 2:3 | 1 |
| 27 | PSV | 2 | 0 | 1 | 1 | 2:4 | 1 |
| 28 | FC Copenhagen | 2 | 0 | 1 | 1 | 2:4 | 1 |
| 29 | Olympiacos | 2 | 0 | 1 | 1 | 0:2 | 1 |
| 30 | Monaco | 2 | 0 | 1 | 1 | 3:6 | 1 |
| 31 | Slavia Prague | 2 | 0 | 1 | 1 | 2:5 | 1 |
| 32 | Pafos | 2 | 0 | 1 | 1 | 1:5 | 1 |
| 33 | Benfica | 2 | 0 | 0 | 2 | 2:4 | 0 |
| 34 | Athletic Club | 2 | 0 | 0 | 2 | 1:6 | 0 |
| 35 | Ajax | 2 | 0 | 0 | 2 | 0:6 | 0 |
| 36 | Kairat Almaty | 2 | 0 | 0 | 2 | 1:9 | 0 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Atlético Madrid | 1 | 1 | 0 | 0 | 5:1 | 3 |
| 2 | Frankfurt | 1 | 1 | 0 | 0 | 5:1 | 3 |
| 3 | PSG | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 4 | Marseille | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 5 | Dortmund | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 6 | Club Brugge | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 7 | Sporting | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 8 | Inter Milan | 1 | 1 | 0 | 0 | 3:0 | 3 |
| 9 | Bayern Munich | 1 | 1 | 0 | 0 | 3:1 | 3 |
| 10 | Arsenal | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 11 | Qarabag FK | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 12 | Man City | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 13 | Liverpool | 1 | 1 | 0 | 0 | 3:2 | 3 |
| 14 | Real Madrid | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 15 | Napoli | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 16 | Atalanta | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 17 | Tottenham | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 18 | Chelsea | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 19 | Galatasaray | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 20 | Juventus | 1 | 0 | 1 | 0 | 4:4 | 1 |
| 21 | Bodo/Glimt | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 22 | Villarreal | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 23 | FC Copenhagen | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 24 | Monaco | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 25 | Slavia Prague | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 26 | Leverkusen | 1 | 0 | 1 | 0 | 1:1 | 1 |
| 27 | Olympiacos | 1 | 0 | 1 | 0 | 0:0 | 1 |
| 28 | Benfica | 1 | 0 | 0 | 1 | 2:3 | 0 |
| 29 | Newcastle | 1 | 0 | 0 | 1 | 1:2 | 0 |
| 30 | Barcelona | 1 | 0 | 0 | 1 | 1:2 | 0 |
| 31 | PSV | 1 | 0 | 0 | 1 | 1:3 | 0 |
| 32 | Athletic Club | 1 | 0 | 0 | 1 | 0:2 | 0 |
| 33 | Ajax | 1 | 0 | 0 | 1 | 0:2 | 0 |
| 34 | Pafos | 1 | 0 | 0 | 1 | 1:5 | 0 |
| 35 | Union S-G | 1 | 0 | 0 | 1 | 0:4 | 0 |
| 36 | Kairat Almaty | 1 | 0 | 0 | 1 | 0:5 | 0 |
La Liga Table
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Real Madrid | 9 | 8 | 0 | 1 | 20:9 | 24 |
| 2 | Barcelona | 9 | 7 | 1 | 1 | 24:10 | 22 |
| 3 | Villarreal | 9 | 5 | 2 | 2 | 16:10 | 17 |
| 4 | Atlético Madrid | 9 | 4 | 4 | 1 | 16:10 | 16 |
| 5 | Real Betis | 9 | 4 | 4 | 1 | 15:10 | 16 |
| 6 | Espanyol | 9 | 4 | 3 | 2 | 13:11 | 15 |
| 7 | Elche | 9 | 3 | 5 | 1 | 11:9 | 14 |
| 8 | Athletic Club | 9 | 4 | 2 | 3 | 9:9 | 14 |
| 9 | Sevilla | 9 | 4 | 1 | 4 | 16:14 | 13 |
| 10 | Rayo Vallecano | 9 | 3 | 2 | 4 | 11:10 | 11 |
| 11 | Alavés | 8 | 3 | 2 | 3 | 9:8 | 11 |
| 12 | Getafe | 9 | 3 | 2 | 4 | 9:12 | 11 |
| 13 | Osasuna | 9 | 3 | 1 | 5 | 7:9 | 10 |
| 14 | Levante | 9 | 2 | 2 | 5 | 13:17 | 8 |
| 15 | Mallorca | 9 | 2 | 2 | 5 | 10:14 | 8 |
| 16 | Valencia | 8 | 2 | 2 | 4 | 10:14 | 8 |
| 17 | Celta Vigo | 9 | 0 | 7 | 2 | 8:11 | 7 |
| 18 | Real Sociedad | 9 | 1 | 3 | 5 | 8:13 | 6 |
| 19 | Real Oviedo | 9 | 2 | 0 | 7 | 4:16 | 6 |
| 20 | Girona | 9 | 1 | 3 | 5 | 6:19 | 6 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Villarreal | 5 | 4 | 1 | 0 | 12:3 | 13 |
| 2 | Atlético Madrid | 5 | 4 | 1 | 0 | 12:5 | 13 |
| 3 | Barcelona | 4 | 4 | 0 | 0 | 13:2 | 12 |
| 4 | Real Madrid | 4 | 4 | 0 | 0 | 8:2 | 12 |
| 5 | Elche | 5 | 3 | 2 | 0 | 6:2 | 11 |
| 6 | Osasuna | 4 | 3 | 1 | 0 | 6:2 | 10 |
| 7 | Espanyol | 5 | 3 | 1 | 1 | 9:7 | 10 |
| 8 | Athletic Club | 5 | 3 | 1 | 1 | 7:5 | 10 |
| 9 | Real Betis | 4 | 3 | 0 | 1 | 7:3 | 9 |
| 10 | Valencia | 4 | 2 | 1 | 1 | 7:3 | 7 |
| 11 | Alavés | 4 | 2 | 1 | 1 | 7:5 | 7 |
| 12 | Getafe | 4 | 1 | 2 | 1 | 4:3 | 5 |
| 13 | Celta Vigo | 6 | 0 | 5 | 1 | 5:7 | 5 |
| 14 | Mallorca | 4 | 1 | 2 | 1 | 3:5 | 5 |
| 15 | Sevilla | 5 | 1 | 1 | 3 | 9:10 | 4 |
| 16 | Real Sociedad | 4 | 1 | 1 | 2 | 4:5 | 4 |
| 17 | Girona | 5 | 1 | 1 | 3 | 3:10 | 4 |
| 18 | Real Oviedo | 5 | 1 | 0 | 4 | 2:10 | 3 |
| 19 | Rayo Vallecano | 3 | 0 | 2 | 1 | 2:3 | 2 |
| 20 | Levante | 4 | 0 | 1 | 3 | 5:12 | 1 |
Super League Table
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | PAOK | 7 | 5 | 2 | 0 | 11:5 | 17 |
| 2 | Olympiacos | 7 | 5 | 1 | 1 | 16:5 | 16 |
| 3 | AEK | 7 | 5 | 1 | 1 | 9:5 | 16 |
| 4 | Volos | 7 | 4 | 0 | 3 | 11:10 | 12 |
| 5 | Levadiakos | 7 | 3 | 2 | 2 | 18:9 | 11 |
| 6 | Aris | 7 | 3 | 2 | 2 | 7:8 | 11 |
| 7 | Panathinaikos | 6 | 2 | 3 | 1 | 8:7 | 9 |
| 8 | Kifisia | 7 | 2 | 2 | 3 | 13:13 | 8 |
| 9 | Panetolikos | 7 | 2 | 1 | 4 | 8:14 | 7 |
| 10 | Atromitos | 7 | 1 | 3 | 3 | 7:8 | 6 |
| 11 | OFI Crete | 6 | 2 | 0 | 4 | 8:13 | 6 |
| 12 | Panserraikos | 7 | 1 | 2 | 4 | 5:13 | 5 |
| 13 | Larissa | 7 | 0 | 4 | 3 | 7:13 | 4 |
| 14 | Asteras Tripolis | 7 | 0 | 3 | 4 | 9:14 | 3 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | PAOK | 4 | 3 | 1 | 0 | 4:1 | 10 |
| 2 | Levadiakos | 4 | 3 | 0 | 1 | 13:3 | 9 |
| 3 | Olympiacos | 3 | 3 | 0 | 0 | 10:2 | 9 |
| 4 | AEK | 4 | 3 | 0 | 1 | 4:2 | 9 |
| 5 | Volos | 3 | 2 | 0 | 1 | 4:4 | 6 |
| 6 | Panathinaikos | 3 | 1 | 2 | 0 | 3:2 | 5 |
| 7 | Aris | 4 | 1 | 2 | 1 | 4:4 | 5 |
| 8 | Panserraikos | 3 | 1 | 1 | 1 | 3:3 | 4 |
| 9 | Asteras Tripolis | 3 | 0 | 3 | 0 | 7:7 | 3 |
| 10 | OFI Crete | 3 | 1 | 0 | 2 | 5:5 | 3 |
| 11 | Kifisia | 3 | 1 | 0 | 2 | 5:6 | 3 |
| 12 | Panetolikos | 4 | 1 | 0 | 3 | 6:8 | 3 |
| 13 | Atromitos | 3 | 0 | 2 | 1 | 4:5 | 2 |
| 14 | Larissa | 4 | 0 | 2 | 2 | 4:9 | 2 |
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