Barcelona vs Olympiacos Prediction, Betting Tips, Lineups & Odds | 21 Oct 2025

Champions League Betting Preview: Barcelona vs Olympiacos

Spanish La Liga giants Barcelona host Greek Super League club Olympiacos in this Champions League match at Camp Nou, with kick-off set for 12:45 on Tuesday 21 October. Our betting preview features expert predictions, betting tips, the latest odds, H2H stats, team news and both predicted and confirmed lineups.

Barcelona -2.25 are available at -102 on the Asian Handicap and we need a three-goal winning margin to land a full return. However, we get half our stake returned if the favourites win by two goals against Olympiacos.

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Barcelona won their last game, beating Girona 2-1 at Estadio Olimpico Lluis Companys in La Liga. Los Culés had nine shots on target and boasted 68% possession, with Pedri and Ronald Araujo scoring one goal apiece in the Catalan derby.

Olympiacos won their previous game. It was on the road where Larissa were beaten 2-0 at Alkazar Stadium in the Super League. Jose Luis Mendilibar's team managed four shots on goal and enjoyed 57% possession, with Ayoub El Kaabi scoring twice.

Champions League		G	W	D	L	GF	GA	GD	GD	P
18	Barcelona	5	2	1	2	12	10	2	12:10	7
33	Olympiacos	5	0	2	3	5	13	-8	5:13	2

View Full Table

8 wins, 1 loss and 1 draw, averaging 2.7 goals from 20.2 attempts and 8.3 shots on goal. Barca have had 71.3% possession and 7.3 corners per match. On average, the opposition have scored 1.0 goals from 7.4 attempts and 3.0 shots on goal, while earning 3.9 corners.

Robert Lewandowski leads the way with 6 goals, while Ferran Torres and Raphinha have scored 4 and 3 respectively. Lamine Yamal and Marcus Rashford are tied for the most assists on 4, with goalie Joan Garcia managing 3 clean sheets.

Olympiacos have won 8, lost 1 and drawn 1, with an average of 2.3 goals from 4.8 shots on goal and 9.3 attempts. The Piraeus outfit have averaged 56.1% possession, 6.4 corners taken and 3.3 corners against, while conceding 0.7 goals from 3.5 shots on goal and 5.9 attempts.

Ayoub El Kaabi has landed 7 goals, Chiquinho 5, with Panagiotis Retsos and two others scoring 2. Francisco Ortega, Ayoub El Kaabi and Christos Mouzakitis have clocked up 2 assists each in the previous 10 games.

Confirmed Lineups

Barcelona confirmed lineup (4-2-3-1): Wojciech Szczesny (GK), Jules Kounde, Pau Cubarsi, Eric Garcia, Alejandro Balde, Marc Casado, Pedri, Lamine Yamal, Dro Fernandez, Fermin Lopez, Marcus Rashford.

Olympiacos confirmed lineup (4-2-3-1): Konstantinos Tzolakis (GK), Costinha, Panagiotis Retsos, Lorenzo Pirola, Francisco Ortega, Santiago Hezze, Dani Garcia, Daniel Podence, Chiquinho, Gelson Martins, Ayoub El Kaabi.

Barcelona vs Olympiacos Prediction & Betting Tips

Our Barcelona vs Olympiacos betting guide delivers expert insight, including a main match pick, our corners angle, scoreline advice, standout player props and bet builder recommendations. Dive into each section below for more.

Match Prediction

Barcelona should pack a punch in this Champions League game. We’ll take them at -2.25 which means getting generous odds of -102 and there’s every chance that the favourites can oblige with a handsome win.

Our football picks always stem from lots of research and it begins by looking at the latest Champions League team news and current form. When we have a strong view of what might happen, we match up the latest numbers.

Key Barcelona vs Olympiacos Champions League & league stats:

• The -2.25 line has been covered by Barca in 2 of their last 5 games at home.

The best betting apps make it a 50.5% chance that our pick is settled as a winner. However, our experts think that the probability is close to 60% taking all factors into consideration. This wager can therefore be backed with confidence.

There is regularly the choice to sell goals which potentially provides the chance to secure a larger return. Alternatively, buying goals is a safer option at skinnier odds.

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Our Match Prediction

Barcelona Asian Hcp -2.25 @ -102 Bet Now

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Correct Score Prediction

Barcelona 3 - 0 Olympiacos

We’re betting on Barcelona to secure a 3-0 winning scoreline. Odds of +650 can be taken and it’s great fun to predict a correct score and hopefully land a winner.

Player Prop Picks

Top Pick: Lamine Yamal Under 1.5 Shots On Target -141

Lamine Yamal (Barcelona) hasn't covered the 1.5 shots on goal total in three straight games. We’ll go with the latest numbers and back him to go under the Shots on Target line at odds of -141.

Latest Lamine Yamal Player Prop Odds

Goalscorer

Anytime

-133

First

+280

Shots On Target

Over 1.5

-159

Under 1.5

-108

Shots

Over 4.5

-137

Under 4.5

-

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Pedri to Score +525

Pedri (Barcelona) has scored two goals in his past ten games. Based on the numbers, we are looking to bet the +525 for him to find the net on the Anytime Goalscorer market.

Latest Pedri Player Prop Odds

Goalscorer

Anytime

+525

First

+1400

Shots On Target

Over 0.5

+180

Under 0.5

-345

Shots

Over 1.5

+150

Under 1.5

-

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Corners Prediction

Olympiacos Over 2.5 Corners -104

Olympiacos have had over 2.5 corners in ten consecutive games, while the previous 5 Barcelona matches have seen them concede an average of 5.60 corners. We think it’s possible that Olympiacos will cover the Team Corners line and there are odds of -104 available.

Champions League & League Games

League Games

Last 10 Total For Against

Last 10 at Home Total For Against

Last 10 Away Total For Against

Barcelona

Total

11.80 6.90 4.90

Home

11.10 8.00 3.10

Away

10.90 6.40 4.50

Olympiacos

Total

9.70 7.30 2.40

Home

8.90 7.60 1.30

Away

7.30 4.40 2.90

Latest Corner Odds

Total Corners

Over 9.5

-132

Under 9.5

-108

Barcelona Corners

Over 6.5

-130

Under 6.5

-109

Olympiacos Corners

Over 2.5

-143

Under 2.5

+102

Most Corners

1

-625

X

+950

2

+550

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Barcelona vs Olympiacos Odds

The odds are updated on a frequent basis. You might therefore find that they are different to the ones listed for the above betting predictions.

The latest Full-Time Result odds give Barcelona a 81% chance of triumphing which means that they’re overwhelming -417 favourites to win this Champions League clash. Olympiacos are the outsiders at +1000 which suggests a low likelihood of winning.

If you want to back the favourites to be ahead by the break, then Barca are -159 on the Half-Time Result market. Alternatively, Olympiacos are +650 and the draw is priced at +210.

The odds suggest that Over 2.5 Goals is a strong probability in this exciting contest. Both Teams to Score is a two-way market and, in terms of price, there’s not much to split Yes and No.

If you head to the best football betting sites, you can take your pick when it comes to Champions League matches. The hundreds of markets always ensure lots of choice.

Full-Time Result

1

-417

X

+540

2

+1000

Half-Time Result

1

-159

X

+210

2

+650

Double Chance

1X

-2500

12

-909

X2

+275

Draw No Bet

1

-1429

2

+600

Asian Handicap

1 Hcp -1.75

-122

2 Hcp +1.75

-102

Total Goals

Under 2.5

+200

Over 2.5

-250

Both Teams to Score

Yes

-122

No

-106

Lamine Yamal is the market leader to be First Goalscorer at +280. Alternatively, there’s the chance to back him to find the net at any stage at -133.

Lamine Yamal (Barcelona)

First

-133

Anytime

+280

Marcus Rashford (Barcelona)

First

-116

Anytime

+285

Raphinha (Barcelona)

First

+128

Anytime

+380

Ferran Torres (Barcelona)

First

+140

Anytime

+410

Roony Bardghji (Barcelona)

First

+195

Anytime

+540

Fermín López (Barcelona)

First

+200

Anytime

+550

Ayoub El Kaabi (Olympiacos)

First

+215

Anytime

+600

Roman Yaremchuk (Olympiacos)

First

+480

Anytime

+1300

Mehdi Taremi (Olympiacos)

First

+525

Anytime

+1400

Pedri (Barcelona)

First

+525

Anytime

+1400

Gelson Martins (Olympiacos)

First

+575

Anytime

+1600

Francisco Leonel Lima Silva Machado (Olympiacos)

First

+600

Anytime

+1800

Daniel Podence (Olympiacos)

First

+650

Anytime

+1800

Ronald Araujo (Barcelona)

First

+700

Anytime

+2000

Andreas Christensen (Barcelona)

First

+700

Anytime

+2000

Frenkie de Jong (Barcelona)

First

+800

Anytime

+2000

Eric García (Barcelona)

First

+850

Anytime

+2200

Rodinei (Olympiacos)

First

+850

Anytime

+2200

Gerard Martín (Barcelona)

First

+900

Anytime

+2200

Ayoub El Kaabi (Olympiacos)

Over 0.5

-222

Under 0.5

+125

Roony Bardghji (Barcelona)

Over 0.5

-192

Under 0.5

+120

Fermín López (Barcelona)

Over 0.5

-192

Under 0.5

+112

Lamine Yamal (Barcelona)

Over 1.5

-159

Under 1.5

-108

Marcus Rashford (Barcelona)

Over 1.5

-119

Under 1.5

-141

Raphinha (Barcelona)

Over 1.5

+125

Under 1.5

-200

Roman Yaremchuk (Olympiacos)

Over 0.5

+130

Under 0.5

-208

Mehdi Taremi (Olympiacos)

Over 0.5

+145

Under 0.5

-238

Ferran Torres (Barcelona)

Over 1.5

+150

Under 1.5

-250

Gelson Martins (Olympiacos)

Over 0.5

+160

Under 0.5

-294

Daniel Podence (Olympiacos)

Over 0.5

+180

Under 0.5

-345

Pedri (Barcelona)

Over 0.5

+180

Under 0.5

-345

Francisco Leonel Lima Silva Machado (Olympiacos)

Over 0.5

+200

Under 0.5

-400

Ronald Araujo (Barcelona)

Over 0.5

+290

Under 0.5

-588

Andreas Christensen (Barcelona)

Over 0.5

+290

Under 0.5

-526

Rodinei (Olympiacos)

Over 0.5

+300

Under 0.5

-625

Frenkie de Jong (Barcelona)

Over 0.5

+310

Under 0.5

-667

Eric García (Barcelona)

Over 0.5

+350

Under 0.5

-1000

Gerard Martín (Barcelona)

Over 0.5

+370

Under 0.5

-909

Lamine Yamal (Barcelona)

Over 4.5

-137

Under 4.5

-

Marcus Rashford (Barcelona)

Over 3.5

-152

Under 3.5

-

Raphinha (Barcelona)

Over 3.5

-105

Under 3.5

-

Fermín López (Barcelona)

Over 3.5

-137

Under 3.5

-

Ferran Torres (Barcelona)

Over 2.5

-154

Under 2.5

-

Roony Bardghji (Barcelona)

Over 2.5

+105

Under 2.5

-

Ayoub El Kaabi (Olympiacos)

Over 2.5

-133

Under 2.5

-

Roman Yaremchuk (Olympiacos)

Over 1.5

+140

Under 1.5

-

Pedri (Barcelona)

Over 1.5

+150

Under 1.5

-

Daniel Podence (Olympiacos)

Over 1.5

+120

Under 1.5

-

Mehdi Taremi (Olympiacos)

Over 0.5

-238

Under 0.5

-

Gelson Martins (Olympiacos)

Over 0.5

-233

Under 0.5

-

Francisco Leonel Lima Silva Machado (Olympiacos)

Over 0.5

-204

Under 0.5

-

Rodinei (Olympiacos)

Over 0.5

-102

Under 0.5

-

Latest Champions League and domestic league stats. Full Time Result, Goals, Corners and Possession.

Barcelona Stats

Olympiacos Stats

Full-Time Result

• 8 wins, 1 defeat and 1 draw in the previous 10 matches
• 8 wins, 1 defeat and 1 draw in the previous 10 home matches

Full-Time Result

• 8 wins, 1 defeat and 1 draw in the previous 10 matches
• 7 wins, 2 defeats and 1 draw in the previous 10 away matches

Goals

• An average of 2.70 goals scored and 1.00 conceded in the previous 10 matches
• An average of 2.90 goals scored and 1.30 conceded in the previous 10 home matches
• An average of 3.70 goals per game in the previous 10 matches
• An average of 4.20 goals per game in the previous 10 home matches
• BTTS Yes in 6 of the previous 10 matches
• BTTS Yes in 7 of the previous 10 home matches
• Over 2.5 Goals in 9 of the previous 10 matches
• Over 2.5 Goals in 8 of the previous 10 home matches

Goals

• An average of 2.30 goals scored and 0.70 conceded in the previous 10 matches
• An average of 1.60 goals scored and 0.50 conceded in the previous 10 away matches
• An average of 3.00 goals per game in the previous 10 matches
• An average of 2.10 goals per game in the previous 10 away matches
• BTTS Yes in 4 of the previous 10 matches
• BTTS Yes in 3 of the previous 10 away matches
• Over 2.5 Goals in 4 of the previous 10 matches
• Over 2.5 Goals in 3 of the previous 10 away matches

Corners

• An average of 7.30 corners awarded and 3.90 corners conceded in the last 10 matches
• An average of 8.80 corners awarded and 2.50 corners against in the last 10 home matches
• An average of 11.20 corners awarded in the last 10 matches
• An average of 11.30 corners awarded in the last 10 home matches
• Had the most corners in 8 and least corners in 2 of the last 10 matches
• Had the most corners in 10 and least corners in 0 of the last 10 home matches

Corners

• An average of 6.40 corners awarded and 3.30 corners conceded in the last 10 matches
• An average of 4.50 corners awarded and 2.90 corners against in the last 10 away matches
• An average of 9.70 corners awarded in the last 10 matches
• An average of 7.40 corners awarded in the last 10 away matches
• Had the most corners in 7 and least corners in 2 of the last 10 matches
• Had the most corners in 7 and least corners in 3 of the last 10 away matches

Possession

• An average of 71.30% possession in the last 10 matches
• An average of 71.10% possession in the last 10 home matches
• Most possession in 10 of the last 10 matches
• Most possession in 10 of the last 10 home matches

Possession

• An average of 56.10% possession in the last 10 matches
• An average of 53.80% possession in the last 10 away matches
• Most possession in 6 of the last 10 matches
• Most possession in 5 of the last 10 away matches

Barcelona vs Olympiacos Lineups & Team News

Know who’s in and who’s out for Barca vs Olympiacos before making your bets. We’ll have the predicted and confirmed Champions League lineups for you plus all the latest on player injuries.

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