Olympiacos vs PSV Prediction, Betting Tips, Lineups & Odds | 04 Nov 2025
Champions League Betting Preview: Olympiacos vs PSV
Greek Super League side Olympiacos host Dutch Eredivisie outfit PSV in this Champions League match at Karaiskakis Stadium, with kick-off set for 15:00 on Tuesday 4 November. Our betting preview features expert predictions, betting tips, the latest odds, H2H stats, team news and both predicted and confirmed lineups.
Goals Should Be On the Cards
We can’t pass up the chance to bet on odds of -143 for Over 2.5 on the Total Goals market. The stats imply that Olympiacos and PSV will produce at least three goals and we’ll play this selection with confidence.
Thinking we’ll see more than a couple of goals? Grab the latest BetMGM promo code and check out our review before placing your bet.
Each Team Bidding to Secure Another Win
Olympiacos were victorious when they last played, landing a 2-1 Super League home success against Aris Thessaloniki at Karaiskakis Stadium. Jose Luis Mendilibar's team had most of the ball enjoying 61% possession and five shots on target, with Daniel Podence and Mehdi Taremi each scoring one goal.
PSV Eindhoven claimed a 5-2 Eredivisie home win over Fortuna Sittard at Philips Stadion in their previous game. The Peasants had six shots on goal and enjoyed 63% possession, with Ismael Saibari finding the net twice.
In their previous Champions League engagements, Olympiacos lost 6-1 away to Barcelona, with PSV landing a 6-2 home win over Napoli.
| Champions League | G | W | D | L | GF | GA | GD | GD | P | |
|---|---|---|---|---|---|---|---|---|---|---|
| 16 | PSV |
3 | 1 | 1 | 1 | 8 | 6 | 2 | 8:6 | 4 |
| 33 | Olympiacos |
3 | 0 | 1 | 2 | 1 | 8 | -7 | 1:8 | 1 |
Olympiacos have 5 wins, 3 losses and 2 draws, averaging 1.7 goals from 4.5 shots on goal and 10.4 attempts. The Legend have averaged 53.5% possession and 5.9 corners per match, with the opposition scoring 1.4 goals from 3.1 shots on goal, 6.4 attempts and 2.7 corners.
Ayoub El Kaabi is the top scorer with 6 goals, while Mehdi Taremi has 4 and Chiquinho 3. The leading assistor is Daniel Podence with 3.
PSV – Last 10 League & Champions League GamesPSV have 7 victories, 1 defeat and 2 draws, with an average of 3.1 goals from 6.7 shots on goal and 15.7 attempts. Peter Bosz's side have averaged 58.5% possession, 524.1 passes, 5.6 corners taken and 5.0 corners against, while conceding 1.7 goals from 4.2 shots on goal and 12.0 attempts.
The top scorers have been Ismael Saibari on 10, followed by Dennis Man and Ricardo Pepi with 4. Joey Veerman is top assists provider with 5, while Matej Kovar has recorded one clean sheet in the last 10 games.
Predicted & Confirmed Lineups
Olympiacos predicted lineup (4-2-3-1): Konstantinos Tzolakis (GK), Costinha, Panagiotis Retsos, Lorenzo Pirola, Bruno Onyemaechi, Lorenzo Scipioni, Dani García, Remy Cabella, Mehdi Taremi, Daniel Podence, Ayoub El Kaabi.
PSV predicted lineup (4-3-3): Matej Kovar (GK), Ryan Flamingo, Jerdy Schouten, Yarek Gasiorowski, Anass Salah-Eddine, Ismael Saibari, Mauro Junior, Joey Veerman, Dennis Man, Guus Til, Ivan Perisic.
Olympiacos vs PSV Prediction & Betting Tips
Get fully prepped for Olympiacos vs PSV with our betting guide, featuring our expert match pick, predicted scoreline, sharp corners advice, top player props and a value-focused bet builder.
Match Prediction
We are backing Over 2.5 Goals at -143, with this Champions League game set to be a high-scoring affair. We think the odds are attractive when it comes to at least three goals being scored.
The formbook is always a good place to start ahead of making football predictions. The latest Champions League team news is also an important port of call, while the stats we present always tell an interesting story.
Key Olympiacos vs PSV Champions League & league stats:
Over 2.5 Probability
If you go by the best football betting sites, our pick has a 58.8% chance of delivering a return. After careful examination, our tipsters calculate this probability to be somewhere between 65-70%. It’s why we think it’s worth placing this bet.
There are a selection of different options if you’re looking for bigger odds when it comes to Over 2.5 Goals. If you also have an idea of the winning team, consider the Result & Total Goals market.
Before placing your bets, explore the latest betting offers. Our comprehensive guide features a wide range of welcome bonuses to choose from.
Correct Score Prediction
PSV are available at +800 when it comes to them winning 2-1. We like a correct score play and the chance to bag a nice return if our prediction is right.
Player Prop Picks
Ivan Perisic (PSV) has finished with at least one shot on goal in six of his past nine games on the road. We anticipate that these numbers will prove telling and that he will cover the Shots on Target line at odds of -132.
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Dennis Man (PSV) has managed four goals in his past five matches. We’ll bear these numbers in mind and take odds of +400 that he is able to feature on the scoresheet when we wager on Anytime Goalscorer.
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Corners Prediction
Olympiacos have had an average of 7.80 corners in the past 5 home games, with PSV averaging 4.60 corners in their last 5 away matches. Olympiacos are capable of winning the Corner Match Bet and there’s a great option to get +107 that this happens.
Olympiacos
PSV
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Bet Builder Tips
If you’re up for a same-game multi, then we’ve got more than two goals in total, PSV on the Asian Handicap at +0.25 accompanied by Ivan Perisic (PSV) to have one or more shots on target.
If you’re keen to wager different selections for the same football match, a bet builder will provide a solution. You can predict a number of outcomes and get bigger odds than a single bet. The odds can combine to great effect.
Olympiacos vs PSV Odds
The odds are updated on a frequent basis. You might therefore find that they are different to the ones listed for the above betting predictions.
Bookies Struggling to Separate Teams
You can secure betting odds of +155 when it comes to Olympiacos claiming a Champions League win and the bookmakers have PSV Eindhoven on offer at +163. For those wishing to back the draw, it’s available at +255.
If Olympiacos and PSV play out a draw, then an Asian Handicap -0.25 on the former means a half stake refund. However, a victory for the favourites would mean a full payout at +120.
The lowest odds can be found for Over 2.5 Goals, which means at least three goals being netted. For those expecting both sides to find the net, Both Teams to Score Yes is available at -175.
The recommended betting sites push the boat out to ensure that football bettors can select from hundreds of markets. You can access them for every Champions League game before making a decision.
Ayoub El Kaabi Top of First Goalscorer List
Ayoub El Kaabi is the First Goalscorer favourite at +320. Alternatively, there’s the opportunity to simply back him to find the net anytime at +114.
Latest Champions League and domestic league stats. Full Time Result, Goals, Corners and Possession.
Olympiacos Stats
PSV Stats
- 5 wins, 3 defeats and 2 draws in the previous 10 matches
- 9 wins and 1 draw in the previous 10 home matches
- 7 wins, 1 defeat and 2 draws in the previous 10 matches
- 9 wins and 1 draw in the previous 10 away matches
- An average of 1.70 goals scored and 1.40 conceded in the previous 10 matches
- An average of 2.40 goals scored and 0.70 conceded in the previous 10 home matches
- An average of 3.10 goals per game in the previous 10 matches
- An average of 3.10 goals per game in the previous 10 home matches
- BTTS Yes in 5 of the previous 10 matches
- BTTS Yes in 4 of the previous 10 home matches
- Over 2.5 Goals in 5 of the previous 10 matches
- Over 2.5 Goals in 5 of the previous 10 home matches
- An average of 3.10 goals scored and 1.70 conceded in the previous 10 matches
- An average of 2.90 goals scored and 1.20 conceded in the previous 10 away matches
- An average of 4.80 goals per game in the previous 10 matches
- An average of 4.10 goals per game in the previous 10 away matches
- BTTS Yes in 9 of the previous 10 matches
- BTTS Yes in 8 of the previous 10 away matches
- Over 2.5 Goals in 9 of the previous 10 matches
- Over 2.5 Goals in 8 of the previous 10 away matches
- An average of 5.90 corners awarded and 2.70 corners conceded in the last 10 matches
- An average of 7.20 corners awarded and 2.20 corners against in the last 10 home matches
- An average of 8.60 corners awarded in the last 10 matches
- An average of 9.40 corners awarded in the last 10 home matches
- Had the most corners in 7 and least corners in 2 of the last 10 matches
- Had the most corners in 7 and least corners in 1 of the last 10 home matches
- An average of 5.60 corners awarded and 5.00 corners conceded in the last 10 matches
- An average of 6.00 corners awarded and 4.10 corners against in the last 10 away matches
- An average of 10.60 corners awarded in the last 10 matches
- An average of 10.10 corners awarded in the last 10 away matches
- Had the most corners in 5 and least corners in 4 of the last 10 matches
- Had the most corners in 6 and least corners in 4 of the last 10 away matches
- An average of 53.50% possession in the last 10 matches
- An average of 60.40% possession in the last 10 home matches
- Most possession in 6 of the last 10 matches
- Most possession in 9 of the last 10 home matches
Olympiacos vs PSV Lineups & Team News
Before making your bets, take a look at the Olympiacos vs PSV team news. We’ll bring you the expected and confirmed lineups for the Champions League along with up-to-date injury news.
Olympiacos Predicted Lineup 4-2-3-1
PSV Eindhoven Predicted Lineup 4-3-3
Olympiacos Predicted Lineup 4-2-3-1
PSV Eindhoven Predicted Lineup 4-3-3
Previous Olympiacos Lineups
Previous PSV Lineups
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | PSG | 3 | 3 | 0 | 0 | 13:3 | 9 |
| 2 | Bayern Munich | 3 | 3 | 0 | 0 | 12:2 | 9 |
| 3 | Inter Milan | 3 | 3 | 0 | 0 | 9:0 | 9 |
| 4 | Arsenal | 3 | 3 | 0 | 0 | 8:0 | 9 |
| 5 | Real Madrid | 3 | 3 | 0 | 0 | 8:1 | 9 |
| 6 | Dortmund | 3 | 2 | 1 | 0 | 12:7 | 7 |
| 7 | Man City | 3 | 2 | 1 | 0 | 6:2 | 7 |
| 8 | Newcastle | 3 | 2 | 0 | 1 | 8:2 | 6 |
| 9 | Barcelona | 3 | 2 | 0 | 1 | 9:4 | 6 |
| 10 | Liverpool | 3 | 2 | 0 | 1 | 8:4 | 6 |
| 11 | Chelsea | 3 | 2 | 0 | 1 | 7:4 | 6 |
| 11 | Sporting | 3 | 2 | 0 | 1 | 7:4 | 6 |
| 13 | Qarabag FK | 3 | 2 | 0 | 1 | 6:5 | 6 |
| 14 | Galatasaray | 3 | 2 | 0 | 1 | 5:6 | 6 |
| 15 | Tottenham | 3 | 1 | 2 | 0 | 3:2 | 5 |
| 16 | PSV | 3 | 1 | 1 | 1 | 8:6 | 4 |
| 17 | Atalanta | 3 | 1 | 1 | 1 | 2:5 | 4 |
| 18 | Marseille | 3 | 1 | 0 | 2 | 6:4 | 3 |
| 19 | Atlético Madrid | 3 | 1 | 0 | 2 | 7:8 | 3 |
| 20 | Club Brugge | 3 | 1 | 0 | 2 | 5:7 | 3 |
| 21 | Athletic Club | 3 | 1 | 0 | 2 | 4:7 | 3 |
| 22 | Frankfurt | 3 | 1 | 0 | 2 | 7:11 | 3 |
| 23 | Napoli | 3 | 1 | 0 | 2 | 4:9 | 3 |
| 24 | Union S-G | 3 | 1 | 0 | 2 | 3:9 | 3 |
| 25 | Juventus | 3 | 0 | 2 | 1 | 6:7 | 2 |
| 26 | Bodo/Glimt | 3 | 0 | 2 | 1 | 5:7 | 2 |
| 27 | Monaco | 3 | 0 | 2 | 1 | 3:6 | 2 |
| 28 | Slavia Prague | 3 | 0 | 2 | 1 | 2:5 | 2 |
| 29 | Pafos | 3 | 0 | 2 | 1 | 1:5 | 2 |
| 30 | Leverkusen | 3 | 0 | 2 | 1 | 5:10 | 2 |
| 31 | Villarreal | 3 | 0 | 1 | 2 | 2:5 | 1 |
| 32 | FC Copenhagen | 3 | 0 | 1 | 2 | 4:8 | 1 |
| 33 | Olympiacos | 3 | 0 | 1 | 2 | 1:8 | 1 |
| 34 | Kairat Almaty | 3 | 0 | 1 | 2 | 1:9 | 1 |
| 35 | Benfica | 3 | 0 | 0 | 3 | 2:7 | 0 |
| 36 | Ajax | 3 | 0 | 0 | 3 | 1:11 | 0 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Bayern Munich | 2 | 2 | 0 | 0 | 7:1 | 6 |
| 2 | Arsenal | 2 | 2 | 0 | 0 | 6:0 | 6 |
| 3 | Chelsea | 2 | 2 | 0 | 0 | 6:1 | 6 |
| 4 | Sporting | 2 | 2 | 0 | 0 | 6:2 | 6 |
| 5 | Galatasaray | 2 | 2 | 0 | 0 | 4:1 | 6 |
| 6 | Real Madrid | 2 | 2 | 0 | 0 | 3:1 | 6 |
| 7 | Atalanta | 2 | 1 | 1 | 0 | 2:1 | 4 |
| 8 | Barcelona | 2 | 1 | 0 | 1 | 7:3 | 3 |
| 9 | Atlético Madrid | 1 | 1 | 0 | 0 | 5:1 | 3 |
| 10 | PSG | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 11 | Marseille | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 12 | Dortmund | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 13 | Club Brugge | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 14 | Inter Milan | 1 | 1 | 0 | 0 | 3:0 | 3 |
| 15 | PSV | 2 | 1 | 0 | 1 | 7:5 | 3 |
| 16 | Newcastle | 2 | 1 | 0 | 1 | 4:2 | 3 |
| 17 | Man City | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 18 | Qarabag FK | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 19 | Liverpool | 1 | 1 | 0 | 0 | 3:2 | 3 |
| 20 | Napoli | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 21 | Tottenham | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 22 | Frankfurt | 2 | 1 | 0 | 1 | 6:6 | 3 |
| 23 | Athletic Club | 2 | 1 | 0 | 1 | 3:3 | 3 |
| 24 | Monaco | 2 | 0 | 2 | 0 | 2:2 | 2 |
| 25 | Juventus | 1 | 0 | 1 | 0 | 4:4 | 1 |
| 26 | Bodo/Glimt | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 27 | Slavia Prague | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 28 | Olympiacos | 1 | 0 | 1 | 0 | 0:0 | 1 |
| 29 | FC Copenhagen | 2 | 0 | 1 | 1 | 4:6 | 1 |
| 30 | Villarreal | 2 | 0 | 1 | 1 | 2:4 | 1 |
| 31 | Leverkusen | 2 | 0 | 1 | 1 | 3:8 | 1 |
| 32 | Kairat Almaty | 2 | 0 | 1 | 1 | 0:5 | 1 |
| 33 | Benfica | 1 | 0 | 0 | 1 | 2:3 | 0 |
| 34 | Ajax | 1 | 0 | 0 | 1 | 0:2 | 0 |
| 35 | Pafos | 1 | 0 | 0 | 1 | 1:5 | 0 |
| 36 | Union S-G | 2 | 0 | 0 | 2 | 0:8 | 0 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | PAOK | 9 | 7 | 2 | 0 | 19:5 | 23 |
| 2 | Olympiacos | 9 | 7 | 1 | 1 | 20:6 | 22 |
| 3 | AEK | 9 | 6 | 1 | 2 | 10:7 | 19 |
| 4 | Levadiakos | 9 | 4 | 3 | 2 | 21:10 | 15 |
| 5 | Volos | 9 | 5 | 0 | 4 | 12:13 | 15 |
| 6 | Aris | 9 | 3 | 3 | 3 | 9:11 | 12 |
| 7 | Kifisia | 9 | 3 | 3 | 3 | 16:15 | 12 |
| 8 | Panathinaikos | 8 | 3 | 3 | 2 | 10:8 | 12 |
| 9 | Atromitos | 9 | 2 | 3 | 4 | 11:11 | 9 |
| 10 | Panetolikos | 9 | 2 | 2 | 5 | 9:16 | 8 |
| 11 | Larissa | 9 | 1 | 4 | 4 | 9:15 | 7 |
| 12 | OFI Crete | 7 | 2 | 0 | 5 | 9:16 | 6 |
| 13 | Panserraikos | 9 | 1 | 2 | 6 | 5:20 | 5 |
| 14 | Asteras Tripolis | 8 | 0 | 3 | 5 | 9:16 | 3 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Olympiacos | 5 | 5 | 0 | 0 | 14:3 | 15 |
| 2 | PAOK | 5 | 4 | 1 | 0 | 7:1 | 13 |
| 3 | AEK | 5 | 4 | 0 | 1 | 5:2 | 12 |
| 4 | Levadiakos | 5 | 3 | 1 | 1 | 14:4 | 10 |
| 5 | Volos | 4 | 3 | 0 | 1 | 5:4 | 9 |
| 6 | Panathinaikos | 4 | 2 | 2 | 0 | 5:2 | 8 |
| 7 | Aris | 4 | 1 | 2 | 1 | 4:4 | 5 |
| 8 | Kifisia | 4 | 1 | 1 | 2 | 6:7 | 4 |
| 9 | Panserraikos | 5 | 1 | 1 | 3 | 3:10 | 4 |
| 10 | Asteras Tripolis | 3 | 0 | 3 | 0 | 7:7 | 3 |
| 11 | Panetolikos | 4 | 1 | 0 | 3 | 6:8 | 3 |
| 12 | OFI Crete | 4 | 1 | 0 | 3 | 6:8 | 3 |
| 13 | Atromitos | 4 | 0 | 2 | 2 | 5:7 | 2 |
| 14 | Larissa | 5 | 0 | 2 | 3 | 4:11 | 2 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Feyenoord | 11 | 9 | 1 | 1 | 30:10 | 28 |
| 2 | PSV | 11 | 9 | 1 | 1 | 35:16 | 28 |
| 3 | AZ Alkmaar | 11 | 7 | 3 | 1 | 24:13 | 24 |
| 4 | Ajax | 11 | 5 | 5 | 1 | 21:15 | 20 |
| 5 | Groningen | 11 | 6 | 1 | 4 | 17:15 | 19 |
| 6 | Utrecht | 11 | 5 | 1 | 5 | 20:15 | 16 |
| 7 | Sp. Rotterdam | 11 | 5 | 1 | 5 | 14:23 | 16 |
| 8 | NEC Nijmegen | 11 | 4 | 3 | 4 | 27:20 | 15 |
| 9 | Twente | 11 | 4 | 3 | 4 | 20:18 | 15 |
| 10 | SC Heerenveen | 11 | 3 | 5 | 3 | 19:19 | 14 |
| 11 | Go Ahead E. | 11 | 3 | 4 | 4 | 17:17 | 13 |
| 12 | Fortuna Sittard | 11 | 4 | 1 | 6 | 16:20 | 13 |
| 13 | NAC Breda | 11 | 3 | 3 | 5 | 14:19 | 12 |
| 14 | Volendam | 11 | 2 | 4 | 5 | 14:19 | 10 |
| 15 | Excelsior | 11 | 3 | 1 | 7 | 10:21 | 10 |
| 16 | PEC Zwolle | 11 | 2 | 3 | 6 | 13:27 | 9 |
| 17 | Telstar | 11 | 2 | 2 | 7 | 14:21 | 8 |
| 18 | Heracles | 11 | 2 | 0 | 9 | 15:32 | 6 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Feyenoord | 6 | 5 | 0 | 1 | 13:6 | 15 |
| 2 | PSV | 6 | 4 | 1 | 1 | 19:10 | 13 |
| 3 | Utrecht | 6 | 4 | 1 | 1 | 14:5 | 13 |
| 4 | Ajax | 6 | 4 | 1 | 1 | 10:5 | 13 |
| 5 | AZ Alkmaar | 5 | 3 | 2 | 0 | 15:8 | 11 |
| 6 | NEC Nijmegen | 5 | 3 | 1 | 1 | 16:9 | 10 |
| 7 | Groningen | 6 | 3 | 1 | 2 | 9:5 | 10 |
| 8 | Fortuna Sittard | 5 | 3 | 1 | 1 | 8:6 | 10 |
| 9 | NAC Breda | 6 | 3 | 1 | 2 | 8:7 | 10 |
| 10 | SC Heerenveen | 6 | 2 | 3 | 1 | 12:11 | 9 |
| 11 | Volendam | 5 | 2 | 2 | 1 | 9:6 | 8 |
| 12 | Go Ahead E. | 5 | 2 | 2 | 1 | 8:6 | 8 |
| 13 | Twente | 5 | 2 | 1 | 2 | 9:10 | 7 |
| 14 | Sp. Rotterdam | 6 | 2 | 1 | 3 | 7:14 | 7 |
| 15 | Excelsior | 5 | 2 | 0 | 3 | 4:5 | 6 |
| 16 | Heracles | 5 | 2 | 0 | 3 | 13:15 | 6 |
| 17 | Telstar | 6 | 1 | 2 | 3 | 11:14 | 5 |
| 18 | PEC Zwolle | 5 | 1 | 1 | 3 | 3:10 | 4 |
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