Olympiacos vs PSV Prediction, Betting Tips, Lineups & Odds | 04 Nov 2025

Champions League Betting Preview: Olympiacos vs PSV

Greek Super League side Olympiacos host Dutch Eredivisie outfit PSV in this Champions League match at Karaiskakis Stadium, with kick-off set for 15:00 on Tuesday 4 November. Our betting preview features expert predictions, betting tips, the latest odds, H2H stats, team news and both predicted and confirmed lineups.

We can’t pass up the chance to bet on odds of -143 for Over 2.5 on the Total Goals market. The stats imply that Olympiacos and PSV will produce at least three goals and we’ll play this selection with confidence.

Olympiacos were victorious when they last played, landing a 2-1 Super League home success against Aris Thessaloniki at Karaiskakis Stadium. Jose Luis Mendilibar's team had most of the ball enjoying 61% possession and five shots on target, with Daniel Podence and Mehdi Taremi each scoring one goal.

PSV Eindhoven claimed a 5-2 Eredivisie home win over Fortuna Sittard at Philips Stadion in their previous game. The Peasants had six shots on goal and enjoyed 63% possession, with Ismael Saibari finding the net twice.

In their previous Champions League engagements, Olympiacos lost 6-1 away to Barcelona, with PSV landing a 6-2 home win over Napoli.

Champions League		G	W	D	L	GF	GA	GD	GD	P
18	Olympiacos	8	3	2	3	10	14	-4	10:14	11
28	PSV	8	2	2	4	16	16	0	16:16	8

View Full Table

Olympiacos have 5 wins, 3 losses and 2 draws, averaging 1.7 goals from 4.5 shots on goal and 10.4 attempts. The Legend have averaged 53.5% possession and 5.9 corners per match, with the opposition scoring 1.4 goals from 3.1 shots on goal, 6.4 attempts and 2.7 corners.

Ayoub El Kaabi is the top scorer with 6 goals, while Mehdi Taremi has 4 and Chiquinho 3. The leading assistor is Daniel Podence with 3.

PSV have 7 victories, 1 defeat and 2 draws, with an average of 3.1 goals from 6.7 shots on goal and 15.7 attempts. Peter Bosz's side have averaged 58.5% possession, 524.1 passes, 5.6 corners taken and 5.0 corners against, while conceding 1.7 goals from 4.2 shots on goal and 12.0 attempts.

The top scorers have been Ismael Saibari on 10, followed by Dennis Man and Ricardo Pepi with 4. Joey Veerman is top assists provider with 5, while Matej Kovar has recorded one clean sheet in the last 10 games.

Confirmed Lineups

Olympiacos confirmed lineup (4-2-3-1): Konstantinos Tzolakis (GK), Rodinei, Panagiotis Retsos, Lorenzo Pirola, Francisco Ortega, Christos Mouzakitis, Dani Garcia, Gelson Martins, Chiquinho, Daniel Podence, Ayoub El Kaabi.

PSV confirmed lineup (4-3-3): Matej Kovar (GK), Sergino Dest, Jerdy Schouten, Yarek Gasiorowski, Anass Salah-Eddine, Ismael Saibari, Mauro Junior, Joey Veerman, Dennis Man, Guus Til, Ivan Perisic.

Olympiacos vs PSV Prediction & Betting Tips

Get fully prepped for Olympiacos vs PSV with our betting guide, featuring our expert match pick, predicted scoreline, sharp corners advice, top player props and a value-focused bet builder.

Match Prediction

We are backing Over 2.5 Goals at -143, with this Champions League game set to be a high-scoring affair. We think the odds are attractive when it comes to at least three goals being scored.

The formbook is always a good place to start ahead of making football predictions. The latest Champions League team news is also an important port of call, while the stats we present always tell an interesting story.

Key Olympiacos vs PSV Champions League & league stats:

• The 2.5 line has been covered in 3 of the last 5 Olympiacos games.
• The 2.5 line has been covered in 11 of the last 19 Olympiacos games at home.
• The 2.5 line has been covered in the last 5 PSV games.
• The 2.5 line has been covered in 9 of the last 10 PSV games.
• The 2.5 line has been covered in 17 of the last 20 PSV games.

If you go by the best football betting sites, our pick has a 58.8% chance of delivering a return. After careful examination, our tipsters calculate this probability to be somewhere between 65-70%. It’s why we think it’s worth placing this bet.

There are a selection of different options if you’re looking for bigger odds when it comes to Over 2.5 Goals. If you also have an idea of the winning team, consider the Result & Total Goals market.

Before placing your bets, explore the latest betting offers. Our comprehensive guide features a wide range of welcome bonuses to choose from.

Our Match Prediction

Over 2.5 Goals @ -143 Bet Now

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Disclosure: This preview contains affiliate links; we may earn a commission at no extra cost to you. T&Cs apply. We only recommend licensed and regulated operators. See our Editorial Policy. Pick odds and lines reflect the price available at the time of publication (Nov 2, 21:08). Live market odds are updated regularly and may differ. 18+ (or legal age) | Gamble Responsibly.

Correct Score Prediction

Olympiacos 1 - 2 PSV

PSV are available at +800 when it comes to them winning 2-1. We like a correct score play and the chance to bag a nice return if our prediction is right.

Player Prop Picks

Top Pick: Ivan Perisic Over 0.5 Shots On Target -132

Ivan Perisic (PSV) has finished with at least one shot on goal in six of his past nine games on the road. We anticipate that these numbers will prove telling and that he will cover the Shots on Target line at odds of -132.

Latest Ivan Perisic Player Prop Odds

Goalscorer

Anytime

+265

First

+700

Shots On Target

Over 0.5

-133

Under 0.5

-128

Shots

Over 1.5

-172

Under 1.5

-

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Dennis Man to Score +400

Dennis Man (PSV) has managed four goals in his past five matches. We’ll bear these numbers in mind and take odds of +400 that he is able to feature on the scoresheet when we wager on Anytime Goalscorer.

Latest Dennis Man Player Prop Odds

Goalscorer

Anytime

+370

First

+1000

Shots On Target

Over 0.5

+105

Under 0.5

-182

Shots

Over 1.5

-143

Under 1.5

-

Pick odds and lines correct at publication. Live market odds are updated regularly and may differ. T&Cs apply. 18+ (or legal age) | Gamble Responsibly.

Corners Prediction

Olympiacos To Have Most Corners +107

Olympiacos have had an average of 7.80 corners in the past 5 home games, with PSV averaging 4.60 corners in their last 5 away matches. Olympiacos are capable of winning the Corner Match Bet and there’s a great option to get +107 that this happens.

Champions League & League Games

League Games

Last 10 Total For Against

Last 10 at Home Total For Against

Last 10 Away Total For Against

Olympiacos

Total

8.60 5.90 2.70

Home

9.40 7.20 2.20

Away

7.50 3.90 3.60

PSV

Total

10.60 5.60 5.00

Home

11.30 7.20 4.10

Away

10.10 6.00 4.10

Latest Corner Odds

Total Corners

Over 9.5

-110

Under 9.5

-130

Olympiacos Corners

Over 4.5

-120

Under 4.5

-118

PSV Corners

Over 4.5

-115

Under 4.5

-123

Most Corners

1

+104

X

+600

2

+108

Pick odds and lines correct at publication. Live market odds are updated regularly and may differ. T&Cs apply. 18+ (or legal age) | Gamble Responsibly.

Olympiacos vs PSV Odds

The odds and lines below are updated regularly and may differ from the prices shown in our picks, which are captured at the time of publication.

You can secure betting odds of +150 when it comes to PSV Eindhoven claiming a Champions League win and the bookmakers have Olympiacos on offer at +160. For those wishing to back the draw, it’s available at +265.

If PSV and Olympiacos play out a draw, then an Asian Handicap -0.25 on the former means a half stake refund. However, a victory for the favourites would mean a full payout at +118.

The lowest odds can be found for Over 2.5 Goals, which means at least three goals being netted. For those expecting both sides to find the net, Both Teams to Score Yes is available at -227.

The recommended betting sites push the boat out to ensure that football bettors can select from hundreds of markets. You can access them for every Champions League game before making a decision.

Full-Time Result

1

+160

X

+265

2

+150

Half-Time Result

1

+200

X

+155

2

+188

Double Chance

1X

-200

12

-357

X2

-208

Draw No Bet

1

-111

2

-120

Asian Handicap

1 Hcp +0.25

-147

2 Hcp -0.25

+118

Total Goals

Under 2.5

+155

Over 2.5

-192

Both Teams to Score

Yes

-227

No

+170

Ayoub El Kaabi is the First Goalscorer favourite at +280. Alternatively, there’s the opportunity to simply back him to find the net anytime at -122.

Ayoub El Kaabi (Olympiacos)

First

-122

Anytime

+280

Ismael Saibari (PSV)

First

+170

Anytime

+475

Ricardo Pepi (PSV)

First

+188

Anytime

+500

Ivan Perisic (PSV)

First

+265

Anytime

+700

Myron Boadu (PSV)

First

+285

Anytime

+750

Gelson Martins (Olympiacos)

First

+310

Anytime

+800

Guus Til (PSV)

First

+310

Anytime

+850

Francisco Leonel Lima Silva Machado (Olympiacos)

First

+340

Anytime

+900

Paul Wanner (PSV)

First

+350

Anytime

+900

Daniel Podence (Olympiacos)

First

+360

Anytime

+950

Dennis Man (PSV)

First

+370

Anytime

+1000

Couhaib Driouech (PSV)

First

+380

Anytime

+900

Esmir Bajraktarevic (PSV)

First

+400

Anytime

+900

Rodinei (Olympiacos)

First

+450

Anytime

+1200

Joey Veerman (PSV)

First

+475

Anytime

+1300

Gabriel Strefezza "Espeto" (Olympiacos)

First

+500

Anytime

+1300

Santiago Hezze (Olympiacos)

First

+800

Anytime

+2000

Mauro Jaqueson Júnior Ferreira dos Santos (PSV)

First

+800

Anytime

+2200

Francisco Ortega (Olympiacos)

First

+900

Anytime

+2200

Ismael Saibari (PSV)

Over 0.5

-233

Under 0.5

+133

Ricardo Pepi (PSV)

Over 0.5

-213

Under 0.5

+120

Ivan Perisic (PSV)

Over 0.5

-133

Under 0.5

-128

Myron Boadu (PSV)

Over 0.5

-116

Under 0.5

-143

Guus Til (PSV)

Over 0.5

-103

Under 0.5

-164

Daniel Podence (Olympiacos)

Over 0.5

+102

Under 0.5

-175

Gelson Martins (Olympiacos)

Over 0.5

+104

Under 0.5

-172

Dennis Man (PSV)

Over 0.5

+105

Under 0.5

-182

Ayoub El Kaabi (Olympiacos)

Over 1.5

+105

Under 1.5

-179

Francisco Leonel Lima Silva Machado (Olympiacos)

Over 0.5

+112

Under 0.5

-192

Paul Wanner (PSV)

Over 0.5

+116

Under 0.5

-200

Couhaib Driouech (PSV)

Over 0.5

+132

Under 0.5

-233

Esmir Bajraktarevic (PSV)

Over 0.5

+133

Under 0.5

-233

Gabriel Strefezza "Espeto" (Olympiacos)

Over 0.5

+150

Under 0.5

-294

Joey Veerman (PSV)

Over 0.5

+165

Under 0.5

-333

Rodinei (Olympiacos)

Over 0.5

+200

Under 0.5

-417

Mauro Jaqueson Júnior Ferreira dos Santos (PSV)

Over 0.5

+310

Under 0.5

-833

Santiago Hezze (Olympiacos)

Over 0.5

+320

Under 0.5

-833

Francisco Ortega (Olympiacos)

Over 0.5

+360

Under 0.5

-1250

Ayoub El Kaabi (Olympiacos)

Over 3.5

+120

Under 3.5

-

Ismael Saibari (PSV)

Over 3.5

+128

Under 3.5

-

Ricardo Pepi (PSV)

Over 2.5

-100

Under 2.5

-

Daniel Podence (Olympiacos)

Over 2.5

-104

Under 2.5

-

Ivan Perisic (PSV)

Over 1.5

-172

Under 1.5

-

Myron Boadu (PSV)

Over 1.5

-143

Under 1.5

-

Gelson Martins (Olympiacos)

Over 1.5

-123

Under 1.5

-

Guus Til (PSV)

Over 1.5

-182

Under 1.5

-

Francisco Leonel Lima Silva Machado (Olympiacos)

Over 1.5

-128

Under 1.5

-

Paul Wanner (PSV)

Over 1.5

+108

Under 1.5

-

Dennis Man (PSV)

Over 1.5

-143

Under 1.5

-

Couhaib Driouech (PSV)

Over 1.5

+128

Under 1.5

-

Esmir Bajraktarevic (PSV)

Over 1.5

+125

Under 1.5

-

Joey Veerman (PSV)

Over 1.5

+148

Under 1.5

-

Gabriel Strefezza "Espeto" (Olympiacos)

Over 1.5

+106

Under 1.5

-

Rodinei (Olympiacos)

Over 0.5

-208

Under 0.5

-

Latest Champions League and domestic league stats. Full Time Result, Goals, Corners and Possession.

Olympiacos Stats

PSV Stats

Full-Time Result

• 5 wins, 3 defeats and 2 draws in the previous 10 matches
• 9 wins and 1 draw in the previous 10 home matches

Full-Time Result

• 7 wins, 1 defeat and 2 draws in the previous 10 matches
• 9 wins and 1 draw in the previous 10 away matches

Goals

• An average of 1.70 goals scored and 1.40 conceded in the previous 10 matches
• An average of 2.40 goals scored and 0.70 conceded in the previous 10 home matches
• An average of 3.10 goals per game in the previous 10 matches
• An average of 3.10 goals per game in the previous 10 home matches
• BTTS Yes in 5 of the previous 10 matches
• BTTS Yes in 4 of the previous 10 home matches
• Over 2.5 Goals in 5 of the previous 10 matches
• Over 2.5 Goals in 5 of the previous 10 home matches

Goals

• An average of 3.10 goals scored and 1.70 conceded in the previous 10 matches
• An average of 2.90 goals scored and 1.20 conceded in the previous 10 away matches
• An average of 4.80 goals per game in the previous 10 matches
• An average of 4.10 goals per game in the previous 10 away matches
• BTTS Yes in 9 of the previous 10 matches
• BTTS Yes in 8 of the previous 10 away matches
• Over 2.5 Goals in 9 of the previous 10 matches
• Over 2.5 Goals in 8 of the previous 10 away matches

Corners

• An average of 5.90 corners awarded and 2.70 corners conceded in the last 10 matches
• An average of 7.20 corners awarded and 2.20 corners against in the last 10 home matches
• An average of 8.60 corners awarded in the last 10 matches
• An average of 9.40 corners awarded in the last 10 home matches
• Had the most corners in 7 and least corners in 2 of the last 10 matches
• Had the most corners in 7 and least corners in 1 of the last 10 home matches

Corners

• An average of 5.60 corners awarded and 5.00 corners conceded in the last 10 matches
• An average of 6.00 corners awarded and 4.10 corners against in the last 10 away matches
• An average of 10.60 corners awarded in the last 10 matches
• An average of 10.10 corners awarded in the last 10 away matches
• Had the most corners in 5 and least corners in 4 of the last 10 matches
• Had the most corners in 6 and least corners in 4 of the last 10 away matches

Possession

• An average of 53.50% possession in the last 10 matches
• An average of 60.40% possession in the last 10 home matches
• Most possession in 6 of the last 10 matches
• Most possession in 9 of the last 10 home matches

Possession

• An average of 58.50% possession in the last 10 matches
• An average of 59.90% possession in the last 10 away matches
• Most possession in 9 of the last 10 matches
• Most possession in 8 of the last 10 away matches

Olympiacos vs PSV Lineups & Team News

Before making your bets, take a look at the Olympiacos vs PSV team news. We’ll bring you the expected and confirmed lineups for the Champions League along with up-to-date injury news.

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