PSV vs Napoli Prediction, Betting Tips, Lineups & Odds | 21 Oct 2025
Champions League Betting Preview: PSV vs Napoli
Dutch Eredivisie outfit PSV host Italian Serie A club Napoli in this Champions League match at Philips Stadion, with kick-off set for 15:00 on Tuesday 21 October. Our betting preview features expert predictions, betting tips, the latest odds, H2H stats, team news and both predicted and confirmed lineups.
Go Over the Total and Cheer on Goals
Goals could be the order of the day when PSV clash with Napoli and we’ll wager on the Total Goals market. Bettors can secure -161 that Over 2.5 happens and that price looks like a spot of value.
Going with our Total Goals selection? Make sure you’ve got the BetMGM promo code locked in and our review read through.
Napoli Looking to Avoid Another Defeat
PSV Eindhoven were winners last time out. Landing a 2-1 Eredivisie home triumph against Go Ahead Eagles at Philips Stadion. Peter Bosz's side had most of the ball boasting 57% possession and eight shots on target, with Guus Til scoring both goals.
Napoli were defeated in their previous game. On their travels, they suffered a 1-0 Serie A loss against Torino at Stadio Olimpico Grande Torino. Gli Azzurri dominated possession with 69% of the ball and racked up five shots on goal.
When last playing in the Champions League, PSV visited Bayer Leverkusen and drew 1-1, with Napoli winning 2-1 at home to Sporting CP.
| Champions League | G | W | D | L | GF | GA | GD | GD | P | |
|---|---|---|---|---|---|---|---|---|---|---|
| 19 |  Napoli |
2 | 1 | 0 | 1 | 2 | 3 | -1 | 2:3 | 3 |
| 27 |  PSV |
2 | 0 | 1 | 1 | 2 | 4 | -2 | 2:4 | 1 |
PSV have 8 wins, 1 loss and 1 draw, averaging 3.0 goals from 8.0 shots on goal and 19.3 attempts. The Peasants have averaged 62.0% possession, 555.0 passes and 6.8 corners per match, with their opponents getting 1.3 goals from 3.7 shots on goal, 10.8 attempts and 4.1 corners.
Top goalscorers Guus Til and Joey Veerman have found the net 4 times, with Ismael Saibari scoring 3. Ivan Perisic is the leading assists maker on 5, with goalkeeper Matej Kovar keeping 2 clean sheets.
Napoli – Last 10 League & Champions League GamesNapoli have 6 victories, 2 defeats and 2 draws, with an average of 6.0 shots on goal, 16.9 attempts and 1.6 goals. Antonio Conte's men average 64.0% possession, 559.4 passes, 6.8 corners taken and 2.7 corners against them, while 0.9 goals have been conceded from 8.6 attempts and 2.5 shots on goal.
Kevin De Bruyne is top of the team’s scoring charts with 3, while Andre-Frank Zambo Anguissa, Rasmus Hoejlund, Scott McTominay and Romelu Lukaku have 2. Scott McTominay has clocked up 3 assists, with Alex Meret keeping 4 clean sheets in the last 10 games.
Predicted & Confirmed Lineups
PSV predicted lineup (4-3-3): Matej Kovar (GK), Mauro Junior, Armando Obispo, Yarek Gasiorowski, Anass Salah-Eddine, Ismael Saibari, Jerdy Schouten, Joey Veerman, Dennis Man, Guus Til, Ivan Perisic.
Napoli predicted lineup (4-1-4-1): Vanja Milinković-Savić (GK), Giovanni Di Lorenzo, Sam Beukema, Juan Jesus, Mathías Olivera, Billy Gilmour, Matteo Politano, Andre Zambo Anguissa, Kevin De Bruyne, Scott McTominay, Rasmus Højlund.
PSV vs Napoli Prediction & Betting Tips
This expert PSV vs Napoli betting breakdown features our match prediction, a correct score tip, corners analysis, player prop suggestions and a carefully constructed bet builder to guide your wagers.
Match Prediction
We could see the ball hit the net a few times in this Champions League clash, so let’s take the -161 when it comes to Over 2.5. We’re confident of a return based on the available information.
We study the Champions League form as a first port of call and also make sure we’re across any injuries before making our football predictions. Then it’s a case of understanding the sort of narrative that the stats provide.
Key PSV vs Napoli Champions League & league stats:
Over 2.5 Probability
The betting apps are estimating that there is a 61.7% likelihood of this pick landing a return. However, our experts think that the probability sits between 65-70% taking all factors into consideration. The wager can be recommended for this precise reason.
If you’re looking for bigger odds, then consider combining Over 2.5 Goals with other selections. This can be achieved by placing a Bet Builder and there’s some tasty prices available.
Claim bonuses and free bets before placing a wager. Our in-depth guide shows you the best current betting offers.
Correct Score Prediction
1
-
2
Napoli
Our prediction for the correct score is Napoli to land a 2-1 victory and this is available at +700. It’s a fun wager to place which lands a bigger potential return.
Player Prop Picks
Scott McTominay (Napoli) has bagged at least one shot on goal in seven of his past nine games away from home. The numbers imply that he can succeed with our Overs bet and we’re delighted to take the -161 available.
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Kevin De Bruyne (Napoli) has netted three goals in his past five matches away from home. When it comes to him scoring, we think that the +260 available is attractive when betting on the Anytime Goalscorer market.
T&C apply. Gamble responsibly 18+
Corners Prediction
PSV have covered the 4.5 corners line in ten consecutive home matches. The PSV Team Corners line looks attractive and we’re going to take the -133 that it’s covered.
PSV
Napoli
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Bet Builder Tips
Our bet builder is compiled of the following: three or more goals, Napoli on the 1x2 accompanied by PSV to have over 4.5 corners.
A football bet builder is a fantastic way of cheering on different selections within the same game. You’re able to forecast various outcomes, with the odds increasing each time before going ahead and placing this wager.
PSV vs Napoli Odds
The odds are updated on a frequent basis. You might therefore find that they are different to the ones listed for the above betting predictions.
Napoli Betting Favourites to Win
At betting odds of +117, the bookies make Napoli probable winners and there’s a 46% likelihood that the favourites triumph in this Champions League encounter. PSV Eindhoven are the underdogs at +215 which implies a lesser percentage prospect of winning.
A win for Napoli would see a full payout on the Asian Handicap -0.25 option. You can get -114 that they overcome PSV going down this route and half stake refunded if it’s a draw.
The Total Goals market reveals that Over 2.5 Goals is the current betting favourite. If you are expecting both teams to score, there’s the chance to back Yes at -185 on the BTTS market.
The leading football betting sites provide bettors with an abundance of options. For every Champions League match, you’re able to select from hundreds of markets and make the best choice.
Lorenzo Lucca Favourite to Find the Net First
Lorenzo Lucca is available at +180 when it comes to Anytime Goalscorer, with the favourite priced at odds of +430 to find the net first.
Latest Champions League and domestic league stats. Full Time Result, Goals, Corners and Possession.
PSV Stats
Napoli Stats
- 8 wins, 1 defeat and 1 draw in the previous 10 matches
- 7 wins, 2 defeats and 1 draw in the previous 10 home matches
- 6 wins, 2 defeats and 2 draws in the previous 10 matches
- 4 wins, 3 defeats and 3 draws in the previous 10 away matches
- An average of 3.00 goals scored and 1.30 conceded in the previous 10 matches
- An average of 2.90 goals scored and 1.30 conceded in the previous 10 home matches
- An average of 4.30 goals per game in the previous 10 matches
- An average of 4.20 goals per game in the previous 10 home matches
- BTTS Yes in 7 of the previous 10 matches
- BTTS Yes in 7 of the previous 10 home matches
- Over 2.5 Goals in 8 of the previous 10 matches
- Over 2.5 Goals in 8 of the previous 10 home matches
- An average of 1.60 goals scored and 0.90 conceded in the previous 10 matches
- An average of 1.00 goals scored and 0.70 conceded in the previous 10 away matches
- An average of 2.50 goals per game in the previous 10 matches
- An average of 1.70 goals per game in the previous 10 away matches
- BTTS Yes in 5 of the previous 10 matches
- BTTS Yes in 4 of the previous 10 away matches
- Over 2.5 Goals in 5 of the previous 10 matches
- Over 2.5 Goals in 3 of the previous 10 away matches
- An average of 6.80 corners awarded and 4.10 corners conceded in the last 10 matches
- An average of 7.80 corners awarded and 3.10 corners against in the last 10 home matches
- An average of 10.90 corners awarded in the last 10 matches
- An average of 10.90 corners awarded in the last 10 home matches
- Had the most corners in 7 and least corners in 3 of the last 10 matches
- Had the most corners in 10 and least corners in 0 of the last 10 home matches
- An average of 6.80 corners awarded and 2.70 corners conceded in the last 10 matches
- An average of 5.30 corners awarded and 4.20 corners against in the last 10 away matches
- An average of 9.50 corners awarded in the last 10 matches
- An average of 9.50 corners awarded in the last 10 away matches
- Had the most corners in 8 and least corners in 2 of the last 10 matches
- Had the most corners in 6 and least corners in 4 of the last 10 away matches
- An average of 62.00% possession in the last 10 matches
- An average of 65.80% possession in the last 10 home matches
- Most possession in 8 of the last 10 matches
- Most possession in 10 of the last 10 home matches
PSV vs Napoli Lineups & Team News
Know who’s in and who’s out for PSV vs Napoli before making your bets. We’ll keep you posted with predicted and confirmed lineups for the Champions League and all current injury news.
PSV Eindhoven Predicted Lineup 4-3-3
Napoli Predicted Lineup 4-1-4-1
PSV Eindhoven Predicted Lineup 4-3-3
Napoli Predicted Lineup 4-1-4-1
Previous PSV Lineups
Previous Napoli Lineups
PSV Squad
Napoli Squad| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Bayern Munich | 2 | 2 | 0 | 0 | 8:2 | 6 |
| 2 | Real Madrid | 2 | 2 | 0 | 0 | 7:1 | 6 |
| 3 | PSG | 2 | 2 | 0 | 0 | 6:1 | 6 |
| 4 | Inter Milan | 2 | 2 | 0 | 0 | 5:0 | 6 |
| 5 | Arsenal | 2 | 2 | 0 | 0 | 4:0 | 6 |
| 6 | Qarabag FK | 2 | 2 | 0 | 0 | 5:2 | 6 |
| 7 | Dortmund | 2 | 1 | 1 | 0 | 8:5 | 4 |
| 8 | Man City | 2 | 1 | 1 | 0 | 4:2 | 4 |
| 9 | Tottenham | 2 | 1 | 1 | 0 | 3:2 | 4 |
| 10 | Atlético Madrid | 2 | 1 | 0 | 1 | 7:4 | 3 |
| 11 | Newcastle | 2 | 1 | 0 | 1 | 5:2 | 3 |
| 12 | Marseille | 2 | 1 | 0 | 1 | 5:2 | 3 |
| 13 | Club Brugge | 2 | 1 | 0 | 1 | 5:3 | 3 |
| 13 | Sporting | 2 | 1 | 0 | 1 | 5:3 | 3 |
| 15 | Frankfurt | 2 | 1 | 0 | 1 | 6:6 | 3 |
| 16 | Barcelona | 2 | 1 | 0 | 1 | 3:3 | 3 |
| 17 | Liverpool | 2 | 1 | 0 | 1 | 3:3 | 3 |
| 18 | Chelsea | 2 | 1 | 0 | 1 | 2:3 | 3 |
| 19 | Napoli | 2 | 1 | 0 | 1 | 2:3 | 3 |
| 20 | Union S-G | 2 | 1 | 0 | 1 | 3:5 | 3 |
| 21 | Galatasaray | 2 | 1 | 0 | 1 | 2:5 | 3 |
| 22 | Atalanta | 2 | 1 | 0 | 1 | 2:5 | 3 |
| 23 | Juventus | 2 | 0 | 2 | 0 | 6:6 | 2 |
| 24 | Bodo/Glimt | 2 | 0 | 2 | 0 | 4:4 | 2 |
| 25 | Leverkusen | 2 | 0 | 2 | 0 | 3:3 | 2 |
| 26 | Villarreal | 2 | 0 | 1 | 1 | 2:3 | 1 |
| 27 | PSV | 2 | 0 | 1 | 1 | 2:4 | 1 |
| 28 | FC Copenhagen | 2 | 0 | 1 | 1 | 2:4 | 1 |
| 29 | Olympiacos | 2 | 0 | 1 | 1 | 0:2 | 1 |
| 30 | Monaco | 2 | 0 | 1 | 1 | 3:6 | 1 |
| 31 | Slavia Prague | 2 | 0 | 1 | 1 | 2:5 | 1 |
| 32 | Pafos | 2 | 0 | 1 | 1 | 1:5 | 1 |
| 33 | Benfica | 2 | 0 | 0 | 2 | 2:4 | 0 |
| 34 | Athletic Club | 2 | 0 | 0 | 2 | 1:6 | 0 |
| 35 | Ajax | 2 | 0 | 0 | 2 | 0:6 | 0 |
| 36 | Kairat Almaty | 2 | 0 | 0 | 2 | 1:9 | 0 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Atlético Madrid | 1 | 1 | 0 | 0 | 5:1 | 3 |
| 2 | Frankfurt | 1 | 1 | 0 | 0 | 5:1 | 3 |
| 3 | PSG | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 4 | Marseille | 1 | 1 | 0 | 0 | 4:0 | 3 |
| 5 | Dortmund | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 6 | Club Brugge | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 7 | Sporting | 1 | 1 | 0 | 0 | 4:1 | 3 |
| 8 | Inter Milan | 1 | 1 | 0 | 0 | 3:0 | 3 |
| 9 | Bayern Munich | 1 | 1 | 0 | 0 | 3:1 | 3 |
| 10 | Arsenal | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 11 | Qarabag FK | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 12 | Man City | 1 | 1 | 0 | 0 | 2:0 | 3 |
| 13 | Liverpool | 1 | 1 | 0 | 0 | 3:2 | 3 |
| 14 | Real Madrid | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 15 | Napoli | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 16 | Atalanta | 1 | 1 | 0 | 0 | 2:1 | 3 |
| 17 | Tottenham | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 18 | Chelsea | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 19 | Galatasaray | 1 | 1 | 0 | 0 | 1:0 | 3 |
| 20 | Juventus | 1 | 0 | 1 | 0 | 4:4 | 1 |
| 21 | Bodo/Glimt | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 22 | Villarreal | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 23 | FC Copenhagen | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 24 | Monaco | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 25 | Slavia Prague | 1 | 0 | 1 | 0 | 2:2 | 1 |
| 26 | Leverkusen | 1 | 0 | 1 | 0 | 1:1 | 1 |
| 27 | Olympiacos | 1 | 0 | 1 | 0 | 0:0 | 1 |
| 28 | Benfica | 1 | 0 | 0 | 1 | 2:3 | 0 |
| 29 | Newcastle | 1 | 0 | 0 | 1 | 1:2 | 0 |
| 30 | Barcelona | 1 | 0 | 0 | 1 | 1:2 | 0 |
| 31 | PSV | 1 | 0 | 0 | 1 | 1:3 | 0 |
| 32 | Athletic Club | 1 | 0 | 0 | 1 | 0:2 | 0 |
| 33 | Ajax | 1 | 0 | 0 | 1 | 0:2 | 0 |
| 34 | Pafos | 1 | 0 | 0 | 1 | 1:5 | 0 |
| 35 | Union S-G | 1 | 0 | 0 | 1 | 0:4 | 0 |
| 36 | Kairat Almaty | 1 | 0 | 0 | 1 | 0:5 | 0 |
Eredivisie Table
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Feyenoord | 9 | 8 | 1 | 0 | 25:6 | 25 |
| 2 | PSV | 9 | 7 | 1 | 1 | 27:12 | 22 |
| 3 | AZ Alkmaar | 9 | 5 | 3 | 1 | 19:12 | 18 |
| 4 | Ajax | 9 | 4 | 4 | 1 | 17:12 | 16 |
| 5 | Groningen | 9 | 5 | 0 | 4 | 14:13 | 15 |
| 6 | NEC Nijmegen | 9 | 4 | 2 | 3 | 25:17 | 14 |
| 7 | Twente | 9 | 4 | 2 | 3 | 17:14 | 14 |
| 8 | Utrecht | 9 | 4 | 1 | 4 | 18:11 | 13 |
| 9 | Fortuna Sittard | 9 | 4 | 1 | 4 | 13:13 | 13 |
| 10 | Sp. Rotterdam | 9 | 4 | 1 | 4 | 13:22 | 13 |
| 11 | SC Heerenveen | 9 | 3 | 3 | 3 | 15:15 | 12 |
| 12 | Go Ahead E. | 9 | 2 | 4 | 3 | 15:16 | 10 |
| 13 | Excelsior | 9 | 3 | 0 | 6 | 8:17 | 9 |
| 14 | NAC Breda | 9 | 2 | 2 | 5 | 10:16 | 8 |
| 15 | PEC Zwolle | 9 | 2 | 2 | 5 | 9:17 | 8 |
| 16 | Telstar | 9 | 2 | 1 | 6 | 12:18 | 7 |
| 17 | Volendam | 9 | 1 | 4 | 4 | 10:16 | 7 |
| 18 | Heracles | 9 | 1 | 0 | 8 | 7:27 | 3 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Feyenoord | 4 | 4 | 0 | 0 | 8:2 | 12 |
| 2 | Ajax | 5 | 4 | 0 | 1 | 9:4 | 12 |
| 3 | Utrecht | 5 | 3 | 1 | 1 | 13:5 | 10 |
| 4 | NEC Nijmegen | 5 | 3 | 1 | 1 | 16:9 | 10 |
| 5 | PSV | 5 | 3 | 1 | 1 | 14:8 | 10 |
| 6 | Fortuna Sittard | 4 | 3 | 1 | 0 | 7:4 | 10 |
| 7 | Groningen | 5 | 3 | 0 | 2 | 8:4 | 9 |
| 8 | AZ Alkmaar | 4 | 2 | 2 | 0 | 11:7 | 8 |
| 9 | SC Heerenveen | 5 | 2 | 2 | 1 | 9:8 | 8 |
| 10 | Twente | 4 | 2 | 1 | 1 | 7:7 | 7 |
| 11 | NAC Breda | 5 | 2 | 1 | 2 | 7:7 | 7 |
| 12 | Excelsior | 5 | 2 | 0 | 3 | 4:5 | 6 |
| 13 | Go Ahead E. | 4 | 1 | 2 | 1 | 6:6 | 5 |
| 14 | Volendam | 4 | 1 | 2 | 1 | 6:6 | 5 |
| 15 | Telstar | 5 | 1 | 1 | 3 | 9:12 | 4 |
| 16 | Sp. Rotterdam | 4 | 1 | 1 | 2 | 6:13 | 4 |
| 17 | PEC Zwolle | 4 | 1 | 0 | 3 | 1:8 | 3 |
| 18 | Heracles | 4 | 1 | 0 | 3 | 5:13 | 3 |
Serie A Table
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | AC Milan | 7 | 5 | 1 | 1 | 11:4 | 16 |
| 2 | Inter Milan | 7 | 5 | 0 | 2 | 18:8 | 15 |
| 3 | Napoli | 7 | 5 | 0 | 2 | 12:7 | 15 |
| 4 | Roma | 7 | 5 | 0 | 2 | 7:3 | 15 |
| 5 | Bologna | 7 | 4 | 1 | 2 | 11:5 | 13 |
| 6 | Como | 7 | 3 | 3 | 1 | 9:5 | 12 |
| 7 | Juventus | 7 | 3 | 3 | 1 | 9:7 | 12 |
| 8 | Atalanta | 7 | 2 | 5 | 0 | 11:5 | 11 |
| 9 | Sassuolo | 7 | 3 | 1 | 3 | 8:8 | 10 |
| 10 | Cremonese | 6 | 2 | 3 | 1 | 7:8 | 9 |
| 11 | Udinese | 6 | 2 | 2 | 2 | 6:9 | 8 |
| 12 | Lazio | 7 | 2 | 2 | 3 | 10:7 | 8 |
| 13 | Cagliari | 7 | 2 | 2 | 3 | 6:8 | 8 |
| 14 | Torino | 7 | 2 | 2 | 3 | 6:13 | 8 |
| 15 | Parma | 7 | 1 | 3 | 3 | 3:7 | 6 |
| 16 | Lecce | 7 | 1 | 3 | 3 | 5:10 | 6 |
| 17 | Hellas Verona | 7 | 0 | 4 | 3 | 2:9 | 4 |
| 18 | Fiorentina | 7 | 0 | 3 | 4 | 5:10 | 3 |
| 19 | Genoa | 7 | 0 | 3 | 4 | 3:9 | 3 |
| 20 | Pisa | 7 | 0 | 3 | 4 | 3:10 | 3 |
| # | Team | G | W | D | L | +/- | P |
|---|---|---|---|---|---|---|---|
| 1 | Inter Milan | 4 | 3 | 0 | 1 | 12:4 | 9 |
| 2 | Bologna | 3 | 3 | 0 | 0 | 7:1 | 9 |
| 3 | Napoli | 3 | 3 | 0 | 0 | 6:3 | 9 |
| 4 | AC Milan | 4 | 3 | 0 | 1 | 6:4 | 9 |
| 5 | Como | 4 | 2 | 2 | 0 | 6:2 | 8 |
| 6 | Juventus | 4 | 2 | 2 | 0 | 7:4 | 8 |
| 7 | Atalanta | 4 | 1 | 3 | 0 | 6:3 | 6 |
| 8 | Sassuolo | 3 | 2 | 0 | 1 | 4:3 | 6 |
| 9 | Roma | 4 | 2 | 0 | 2 | 3:2 | 6 |
| 10 | Lazio | 3 | 1 | 1 | 1 | 7:4 | 4 |
| 11 | Cremonese | 2 | 1 | 1 | 0 | 3:2 | 4 |
| 12 | Parma | 3 | 1 | 1 | 1 | 3:3 | 4 |
| 13 | Cagliari | 4 | 1 | 1 | 2 | 3:5 | 4 |
| 14 | Torino | 3 | 1 | 1 | 1 | 1:3 | 4 |
| 15 | Hellas Verona | 3 | 0 | 2 | 1 | 1:2 | 2 |
| 16 | Pisa | 4 | 0 | 2 | 2 | 0:2 | 2 |
| 17 | Lecce | 4 | 0 | 2 | 2 | 3:6 | 2 |
| 18 | Udinese | 3 | 0 | 2 | 1 | 2:5 | 2 |
| 19 | Genoa | 4 | 0 | 2 | 2 | 0:4 | 2 |
| 20 | Fiorentina | 3 | 0 | 0 | 3 | 3:7 | 0 |
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